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  6. Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Allylpalladium(II) chloride dimer, Pd 56.0% min, Thermo Scientific Chemicals

Product Code. 11356707
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Quantity:
0.25 g
1 g
5 g
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Description

Allylpalladium(II) chloride dimer is used as an important catalyst in Heck reaction. It reacts with cyclopentadienyl anion to give cyclopentadienyl allyl palladium. It acts as a precatalyst for asymmetric and cross-coupling catalysis. Further, it is used in the preparation of 1,4-diallyl-1,2-dihydroisoquinolines. It is also employed as a catalyst for greener Buchwald-Hartwig coupling reaction and involved in the synthesis of cationic palladium catalysts. In addition, it takes part in preparation of -heterocyclic carbene-palladium-eta3-allyl chloride complex, which is an efficient catalyst for the Suzuki-Miyaura cross-coupling reactions in synthetic chemistry.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 12012-95-2
Molecular Formula C6H10Cl2Pd2
Molecular Weight (g/mol) 365.89
MDL Number MFCD00044874
InChI Key PENAXHPKEVTBLF-UHFFFAOYSA-L
Synonym allylpalladium chloride dimer, bis allyl dichlorodipalladium, diallyldipalladium dichloride, palladium allyl chloride dimer, diallydichlorodipalladium, pi-allyl palladium chloride, allylpalladium ii chloride, bis chloro-pi-allylpalladium, allyl palladium chloride dimer, bis pi-allyl chloropalladium
PubChem CID 61538
IUPAC Name chloropalladium(1+);prop-1-ene
SMILES Cl[Pd].Cl[Pd].c:c:c.c:c:c

Specifications

Melting Point 120°C (decomposition)
Color Yellow
Quantity 0.25 g
Beilstein 4124623
Sensitivity Air and moisture sensitive
Solubility Information Very soluble in dichloromethane and dichloroethane; Slightly soluble in toluene,insoluble in waterSoluble in chloroform,benzene,acetone and dichloromethane,dichloroethane and methanol; Slightly soluble in toluene; Insoluble in water.
Formula Weight 365.85
Concentration or Composition (by Analyte or Components) Pd 56.0% min.
Physical Form Powder
Chemical Name or Material Allylpalladium(II) chloride dimer

Safety and Handling

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Product Identifier
  • Allylpalladium(II) chloride dimer
 Signal Word
  • Warning
 Hazard Category
  • Skin corrosion/irritation Category 2
  • Serious eye damage/eye irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Precautionary Statement
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P405-Store locked up.
  • P501-Dispose of contents/container to .

RUO – Research Use Only

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