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  8. Diphenylphosphoryl azide, 98%, Thermo Scientific Chemicals

Diphenylphosphoryl azide, 98%, Thermo Scientific Chemicals

Product Code. 10178112
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Quantity:
25 g
100 g
500 g
Packaging:
Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

C-X bond formation reagent, For Azidation/Diazo transfer
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 26386-88-9
Molecular Formula C12H10N3O3P
Molecular Weight (g/mol) 275.20
MDL Number MFCD00001987
InChI Key SORGEQQSQGNZFI-UHFFFAOYSA-N
Synonym diphenylphosphoryl azide, diphenyl azidophosphate, diphenylphosphonic azide, diphenyl phosphoryl azide, diphenyl phosphorazidate, phosphorazidic acid, diphenyl ester, azido phenoxy phosphoryl oxy benzene, dppa polymer-bound, diphenylphosphorazidate, unii-gxm91165av
PubChem CID 123414
IUPAC Name [azido(phenoxy)phosphoryl]oxybenzene
SMILES [N-]=[N+]=NP(=O)(OC1=CC=CC=C1)OC1=CC=CC=C1

Specifications

Color Yellow to Amber
Density 1.2730g/mL
Boiling Point 157.0°C (0.2 mmHg)
Flash Point 112°C
Infrared Spectrum Authentic
Assay Percent Range 97.5% min. (GC)
Packaging Glass bottle
Refractive Index 1.5500 to 1.5520
Quantity 100 g
Fieser 04,210; 05,280; 07,138; 08,211; 10,173
Merck Index 15,3366
Specific Gravity 1.273
Solubility Information Solubility in water: insoluble. Other solubilities: soluble in most common organic solvents
Formula Weight 275.19
Percent Purity 98%
Physical Form Liquid
Chemical Name or Material Diphenylphosphoryl azide
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Safety and Handling

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Product Identifier
  • Diphenylphosphoryl azide
 Signal Word
  • Danger
 Hazard Category
  • Acute toxicity Category 3
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Hazard Statement
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H311-Toxic in contact with skin.
  • H331-Toxic if inhaled.
  • H335-May cause respiratory irritation.
  • H301-Toxic if swallowed.
 Precautionary Statement
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
  • P302+P352-IF ON SKIN: Wash with plenty of water/.
  • P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P312-Call a POISON CENTER/doctor/if you feel unwell.

RUO – Research Use Only

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