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Ruthenium(III) 2,4-pentanedionate, Ru 24% min, Thermo Scientific Chemicals
For Hydrogenation
Chemical Identifiers
| CAS | 14284-93-6 |
|---|---|
| Molecular Formula | C15H21O6Ru |
| Molecular Weight (g/mol) | 398.40 |
| MDL Number | MFCD00000030 |
| InChI Key | RTZYCRSRNSTRGC-LNTINUHCSA-K |
| Synonym | ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+ |
| PubChem CID | 5488829 |
| SMILES | [Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O |
Description
Precursor for the preparation of other compounds of ruthenium. Ruthenium(III) 2,4-pentanedionate is employed as a recyclable catalyst for certain organic transformations like the acetylation of phenols, alcohols, and amines under neat conditions. It is also used as a homogeneous catalyst, for example, in the hydrolysis of sodium borohydride and regiospecific tritiation of aromatic carboxylic acids. It is also used as a catalyst for enantioselective hydrogenation of acids such as aryl acrylic acid and aryl propenic acid.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
Chemical Identifiers
| 14284-93-6 | |
| 398.40 | |
| RTZYCRSRNSTRGC-LNTINUHCSA-K | |
| 5488829 |
| C15H21O6Ru | |
| MFCD00000030 | |
| ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+ | |
| [Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O |
Specifications
| 260°C (decomposition) | |
| White | |
| C15H21O6Ru | |
| ruthenium acetylacetonate, ruthenium iii acetylacetonate, acetylacetone ruthenium iii salt, tris 2,4-pentanedionato ruthenium iii, tris pentane-2,4-dionato-o,o' ruthenium, ruthenium, tris 2,4-pentanedionato-o,o'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-kappao,kappao'-, oc-6-11, ruthenium, tris 2,4-pentanedionato-8ci, z-4-oxopent-2-en-2-olate; ruthenium 3+ | |
| RTZYCRSRNSTRGC-LNTINUHCSA-K | |
| (Z)-4-oxopent-2-en-2-olate;ruthenium(3+) | |
| 5488829 | |
| Red crystals |
| 14284-93-6 | |
| Crystalline | |
| MFCD00000030 | |
| Soluble in most organic solvents such as acetone,chlorinated hydrocarbons,alcohols,cyclohexane and benzene. Insoluble in water. | |
| [Ru+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O | |
| 398.40 | |
| 398.4 | |
| Ruthenium(III) 2, 4-pentanedionate, Ru 24% min. |
Safety and Handling
P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c
H315-H319-H335
missing translation for 'einecsNumber' : 238-193-0
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
RUO – Research Use Only