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  6. Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene., Thermo Scientific Chemicals

Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene., Thermo Scientific Chemicals

Product Code. 11480863
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Description

Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Sodium bis(2-methoxyethoxy)aluminum hydride acts as a reducing agent in organic synthesis. It is used to prepare azoxyarenes, azoarenes and hydroazoarenes from nitroarenes. It plays an important role for the conversion of aldehydes, ketones, carboxylic acids, esters, acyl halides and anhydrides to primary alcohols. It is also employed in hydroaluminate alkenes and alkynes. It is utilized in the reduction of lactones and epoxides into diols. Further, it serves as a methylation reagent for aryl-activated compounds. In addition to this, it is involved in the reduction of amides, nitriles and amines to the corresponding amines.

Solubility
Miscible with aromatic hydrocarbons, ether, tetrahydrofuran, dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents and combustible material.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 22722-98-1
Molecular Formula C6H16AlNaO4
MDL Number MFCD00011631
Synonym Sodium dihydrobis(2-methoxyethoxy)aluminate

Specifications

Density 1.02
Flash Point 4°C (39°F)
Linear Formula NaAlH2(OCH2CH2OCH3)2
Quantity 50 g
UN Number UN3399
Sensitivity Moisture sensitive
Merck Index 14,8565
Solubility Information Miscible with aromatic hydrocarbons,ether,tetrahydrofuran,dimethyl ether and dimethylformamide. Immiscible with aliphatic hydrocarbons.
Formula Weight 202.16
Chemical Name or Material Sodium bis(2-methoxyethoxy)aluminum hydride

Safety and Handling

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Product Identifier
  • Sodium bis(2-methoxyethoxy)aluminum hydride, 70% w/w in toluene
 Signal Word
  • Danger
 Hazard Category
  • LONG-TERM AQUATIC HAZARD Chronic 3
  • Aspiration toxicity Category 1
  • Serious eye damage/eye irritation Category 1
  • Flammable liquid Category 2
  • Reproductive toxicity Category 2
  • Skin corrosion/irritation Category 1 B
  • Specific target organ toxicity after repeated exposure Category 2
  • Specific target organ toxicity Category 3
  • Substance which\, in contact with water\, emits flammable gases Category 1
 Hazard Statement
  • H225-Highly flammable liquid and vapour.
  • H260-In contact with water releases flammable gases which may ignite spontaneously.
  • H304-May be fatal if swallowed and enters airways.
  • H314-Causes severe skin burns and eye damage.
  • H318-Causes serious eye damage.
  • H336-May cause drowsiness or dizziness.
  • H361d-Suspected of damaging the unborn child.
  • H373-May cause damage to organs.
  • H412-Harmful to aquatic life with long lasting effects.
  • EUH014-Reacts violently with water.
 Precautionary Statement
  • P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
  • P231+P232-Handle under inert gas. Protect from moisture.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
  • P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
  • P310-Immediately call a POISON CENTER/doctor/.
 Supplemental information
  • MIXTURE LIST-Contains : Sodium bis(2-methoxyethoxy)aluminum hydride, toluene

RUO – Research Use Only

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