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  6. tert-Butyl hydroperoxide, 70% aq. soln., Thermo Scientific Chemicals

tert-Butyl hydroperoxide, 70% aq. soln., Thermo Scientific Chemicals

Product Code. 11451648
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Quantity:
100 mL
500 mL
2500 mL

Description

tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 75-91-2
Molecular Formula C4H10O2
Molecular Weight (g/mol) 90.122
MDL Number MFCD00002130
InChI Key CIHOLLKRGTVIJN-UHFFFAOYSA-N
Synonym tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid
PubChem CID 6410
ChEBI CHEBI:64090
IUPAC Name 2-hydroperoxy-2-methylpropane
SMILES CC(C)(C)OO

Specifications

Melting Point -3°C
Density 0.937
Boiling Point 96°C (decomposition)
Flash Point 43°C (109°F)
Assay Percent Range 70% Aqueous Solution
Linear Formula (CH3)3COOH
Refractive Index 1.387
Quantity 100 mL
UN Number UN3109
Beilstein 1098280
Merck Index 14,1570
Solubility Information Miscible with water and diethyl ether.
Formula Weight 90.12
Concentration or Composition (by Analyte or Components) 70% aq. soln.
Chemical Name or Material tert-Butyl hydroperoxide
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Safety and Handling

Hazard Category
  • Carcinogenicity Category 2
  • Skin sensitiser Category 1
 Hazard Statement
  • H331-Toxic if inhaled.
  • H351-Suspected of causing cancer.

RUO – Research Use Only

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