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Tetra-n-butylammonium fluoride, 1M soln. in THF, Thermo Scientific Chemicals
46.13 € - 440.19 €
Chemical Identifiers
| CAS | 429-41-4 |
|---|---|
| Molecular Formula | C16H36FN |
| Molecular Weight (g/mol) | 261.47 |
| MDL Number | MFCD00011747 |
| InChI Key | FPGGTKZVZWFYPV-UHFFFAOYSA-M |
| Synonym | tetrabutylammonium fluoride, tbaf, tetrabutylazanium fluoride, tetrabutyl ammonium fluoride, tetra-n-butylammonium fluoride, tetrabutylamine, fluoride, n,n,n-tributylbutan-1-aminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride, n,n,n-tributyl-1-butanaminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride 1:1 |
| PubChem CID | 2724141 |
| ChEBI | CHEBI:51990 |
| IUPAC Name | tetrabutylazanium;fluoride |
| SMILES | [F-].CCCC[N+](CCCC)(CCCC)CCCC |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11443940
|
Thermo Scientific Alfa Aesar
A10588.AC |
25 mL |
46.13 €
25mL |
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|
11433254
|
Thermo Scientific Alfa Aesar
A10588.AE |
100 mL |
114.57 €
100mL |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
|
11443254
|
Thermo Scientific Alfa Aesar
A10588.AP |
500 mL |
440.19 €
500mL |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTetra-n-butylammonium fluoride, 1M soln. in THF is used as a reactant for the preparation of triple monoamine reuptake inhibitors as a new generation of antidepressants, oligoribonucleotides with phosphonate-modified linkages, conjugated dienoic acid esters using Suzuki coupling reactions and polyacetylenic glucosides. It plays an important role in aryl alkyl alcohols through Nozaki-Hiyama allylation catalyzed by chiral bipyridyldiol ligands and chromium trichloride. It is also used as a catalyst for the silylation reactions. In addition, it is used as a source of fluoride ion in organic solvents as well as for the deprotection of silyl ether groups.
Solubility
Miscible with terahydrofuran, acetonitrile, dimethyl sulfoxide and organic solvents.
Notes
Store in a cool place. Hygroscopic. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and oxygen.
Chemical Identifiers
| 429-41-4 | |
| 261.47 | |
| FPGGTKZVZWFYPV-UHFFFAOYSA-M | |
| 2724141 | |
| tetrabutylazanium;fluoride |
| C16H36FN | |
| MFCD00011747 | |
| tetrabutylammonium fluoride, tbaf, tetrabutylazanium fluoride, tetrabutyl ammonium fluoride, tetra-n-butylammonium fluoride, tetrabutylamine, fluoride, n,n,n-tributylbutan-1-aminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride, n,n,n-tributyl-1-butanaminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride 1:1 | |
| CHEBI:51990 | |
| [F-].CCCC[N+](CCCC)(CCCC)CCCC |
Specifications
| 429-41-4 | |
| −17°C (1°F) | |
| [CH3(CH2)3]4NF | |
| UN2924 | |
| Hygroscopic | |
| Miscible with terahydrofuran,acetonitrile,dimethyl sulfoxide and organic solvents. | |
| [F-].CCCC[N+](CCCC)(CCCC)CCCC | |
| 261.47 | |
| CHEBI:51990 | |
| 1M soln. in THF |
| 0.903 | |
| C16H36FN | |
| MFCD00011747 | |
| 3570522 | |
| tetrabutylammonium fluoride, tbaf, tetrabutylazanium fluoride, tetrabutyl ammonium fluoride, tetra-n-butylammonium fluoride, tetrabutylamine, fluoride, n,n,n-tributylbutan-1-aminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride, n,n,n-tributyl-1-butanaminium fluoride, 1-butanaminium, n,n,n-tributyl-, fluoride 1:1 | |
| FPGGTKZVZWFYPV-UHFFFAOYSA-M | |
| tetrabutylazanium;fluoride | |
| 2724141 | |
| 261.47 | |
| Tetra-n-butylammonium fluoride |
Safety and Handling
GHS H Statement
H225-H314-H351-H302-H335
Highly flammable liquid and vapor.
Causes severe skin burns and eye damage.
Suspected of causing cancer.
Harmful if swallowed.
May cause respiratory irritation.
P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P281-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c
H225-H314-H335-H336-H351-H373
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missing translation for 'einecsNumber' : 207-057-2
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
Supplemental information
- Tetra-n-butylammonium fluoride, 1M solution in THF
Signal Word
- Danger
Hazard Category
- Acute toxicity Category 4
- Carcinogenicity Category 2
- Serious eye damage/eye irritation Category 1
- Flammable liquid Category 2
- Skin corrosion/irritation Category 1 B
- Specific target organ toxicity Category 3
Hazard Statement
- H225-Highly flammable liquid and vapour.
- H302-Harmful if swallowed.
- H314-Causes severe skin burns and eye damage.
- H318-Causes serious eye damage.
- H335-May cause respiratory irritation.
- H336-May cause drowsiness or dizziness.
- H351-Suspected of causing cancer.
- EUH019-May form explosive peroxides.
Precautionary Statement
- P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
Supplemental information
- MIXTURE LIST-Contains : Tetrahydrofuran, Tetra-n-butylammonium fluoride
RUO – Research Use Only