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Triethylamine trihydrofluoride, ca 37% HF, Thermo Scientific Chemicals
29.04 € - 241.20 €
Chemical Identifiers
| CAS | 73602-61-6 |
|---|---|
| Molecular Formula | C6H18F3N |
| Molecular Weight (g/mol) | 161.212 |
| MDL Number | MFCD00043294 |
| InChI Key | IKGLACJFEHSFNN-UHFFFAOYSA-N |
| Synonym | triethylamine trihydrofluoride, n,n-diethylethanamine trihydrofluoride, triethylammonium fluoride, ethanamine, n,n-diethyl-, trihydrofluoride, triethylamine trishydrofluoride, hydrogen fluoride in triethylamine, hf in triethylamine, triethylaminetrihydrofluoride, hydrogen fluoride triethylamine, ethanamine, n,n-diethyl-, hydrofluoride 1:3 |
| PubChem CID | 175505 |
| IUPAC Name | N,N-diethylethanamine;trihydrofluoride |
| SMILES | CCN(CC)CC.F.F.F |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11393516
|
Thermo Scientific Alfa Aesar
L14417.06 |
5 g |
29.04 €
5g |
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|
11303526
|
Thermo Scientific Alfa Aesar
L14417.14 |
25 g |
79.80 €
25g |
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|
11313526
|
Thermo Scientific Alfa Aesar
L14417.22 |
100 g |
241.20 €
100g |
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Description
Triethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsTriethylamine trihydrofluoride acts as a mild and selective fluorinating agent used in the synthesis of acid fluorides and alkyl fluorides. It is also used in the synthesis of vicinal difluorides from epoxides, 3-fluoroazetidine. It is utilized as a selective reagent for the cleavage of O-silyl groups in carbohydrates, nucleotides and cyanohydrins. It is actively involved in the electrochemical fluorodeiodination of alkyl iodides and fluorodesilylation in beta-lactams.
Solubility
Miscible with water, chloroform and hexanes.
Notes
Hygroscopic. Incompatible with strong oxidizing agents and glass.
Chemical Identifiers
| 73602-61-6 | |
| 161.212 | |
| IKGLACJFEHSFNN-UHFFFAOYSA-N | |
| 175505 | |
| CCN(CC)CC.F.F.F |
| C6H18F3N | |
| MFCD00043294 | |
| triethylamine trihydrofluoride, n,n-diethylethanamine trihydrofluoride, triethylammonium fluoride, ethanamine, n,n-diethyl-, trihydrofluoride, triethylamine trishydrofluoride, hydrogen fluoride in triethylamine, hf in triethylamine, triethylaminetrihydrofluoride, hydrogen fluoride triethylamine, ethanamine, n,n-diethyl-, hydrofluoride 1:3 | |
| N,N-diethylethanamine;trihydrofluoride |
Specifications
| 73602-61-6 | |
| 0.99 | |
| 87°C (188°F) | |
| (CH3CH2)3N·3HF | |
| MFCD00043294 | |
| 5522945 | |
| triethylamine trihydrofluoride, n,n-diethylethanamine trihydrofluoride, triethylammonium fluoride, ethanamine, n,n-diethyl-, trihydrofluoride, triethylamine trishydrofluoride, hydrogen fluoride in triethylamine, hf in triethylamine, triethylaminetrihydrofluoride, hydrogen fluoride triethylamine, ethanamine, n,n-diethyl-, hydrofluoride 1:3 | |
| IKGLACJFEHSFNN-UHFFFAOYSA-N | |
| N,N-diethylethanamine;trihydrofluoride | |
| 175505 | |
| ≈37% HF |
| -29°C | |
| 70°C (15 mmHg) | |
| C6H18F3N | |
| 1.3915 | |
| UN1790 | |
| Hygroscopic | |
| Miscible with water,chloroform and hexanes. | |
| CCN(CC)CC.F.F.F | |
| 161.212 | |
| 161.21 | |
| Triethylamine trihydrofluoride |
Safety and Handling
GHS H Statement
H300-H310-H330-H314-H318-H227
Fatal if swallowed.
Fatal in contact with skin.
Fatal if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.
P210-P235-P260-P262-P264b-P270-P271-P280-P284-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c
H227-H300+H310+H330-H314-H335
missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: HYDROFLUORIC ACID
missing translation for 'einecsNumber' : 277-550-5
missing translation for 'tsca' : Yes
Recommended Storage : Ambient temperatures; Store under Nitrogen
Product Identifier
Signal Word
Hazard Category
Hazard Statement
Precautionary Statement
Supplemental information
- Triethylamine trihydrofluoride, ca 37% HF
Signal Word
- Danger
Hazard Category
- Acute toxicity Category 1
- Acute toxicity Category 2
- Serious eye damage/eye irritation Category 1
- Substances and mixtures corrosive to metals Category 1
- Skin corrosion/irritation Category 1 A
Hazard Statement
- H290-May be corrosive to metals.
- H300-Fatal if swallowed.
- H310-Fatal in contact with skin.
- H314-Causes severe skin burns and eye damage.
- H318-Causes serious eye damage.
- H330-Fatal if inhaled.
Precautionary Statement
- P280-Wear protective gloves/protective clothing/eye protection/face protection.
- P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
- P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
- P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
- P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
- P310-Immediately call a POISON CENTER/doctor/.
- P362+P364-Take off contaminated clothing and wash it before reuse.
Supplemental information
- MIXTURE LIST-Contains : Triethylammonium fluoride, Hydrofluoricacid
RUO – Research Use Only
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