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(Trifluoromethyl)trimethylsilane, 95%, Thermo Scientific Chemicals
52.61 € - 344.72 €
Chemical Identifiers
| CAS | 81290-20-2 |
|---|---|
| Molecular Formula | C5H11F3Si |
| Molecular Weight (g/mol) | 156.22 |
| MDL Number | MFCD00145454 |
| InChI Key | MTYSDPUZDZURPP-UHFFFAOYSA-N |
| Synonym | trifluoromethyl trimethylsilane, trimethyl trifluoromethyl silane, trifluoromethyltrimethylsilane, ruppert's reagent, tms-cf3, tfmtms, silane, trimethyl trifluoromethyl, unii-a009786qpj, trimethylsilyl trifluoromethane, ruppert-prakash reagent |
| PubChem CID | 552549 |
| IUPAC Name | trimethyl(trifluoromethyl)silane |
| SMILES | CC(C)(C)[SiH2]C(F)(F)F |
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|---|---|---|---|---|---|---|---|---|---|
| Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
|
11434237
|
Thermo Scientific Alfa Aesar
B20347.03 |
1 g |
52.61 €
1g |
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|
11444237
|
Thermo Scientific Alfa Aesar
B20347.06 |
5 g |
110.00 €
5g |
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|
11454237
|
Thermo Scientific Alfa Aesar
B20347.14 |
25 g |
344.72 €
25g |
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Description
It is employed as a valuable reagent for trifluoromethylation of electrophilic substrates. It is also use an the nucleophilic addition of the trifluoromethyl group to aldehydes and ketones. It generates trifluoromethide with catalytic amounts of F- (TBAF or CsF) and reacts with carbonyl compounds to produce trifluoromethylated alcohols.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIt is employed as a valuable reagent for trifluoromethylation of electrophilic substrates. It is also use an the nucleophilic addition of the trifluoromethyl group to aldehydes and ketones. It generates trifluoromethide with catalytic amounts of F- (TBAF or CsF) and reacts with carbonyl compounds to produce trifluoromethylated alcohols.
Solubility
Soluble in alcohol, THF, ether, dichloromethane, aromatic and aliphatic hydrocarbons. Soluble in water(with white smokes).
Notes
Moisture sensitive. Store away from oxidizing agents and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas.
Chemical Identifiers
| 81290-20-2 | |
| 156.22 | |
| MTYSDPUZDZURPP-UHFFFAOYSA-N | |
| 552549 | |
| CC(C)(C)[SiH2]C(F)(F)F |
| C5H11F3Si | |
| MFCD00145454 | |
| trifluoromethyl trimethylsilane, trimethyl trifluoromethyl silane, trifluoromethyltrimethylsilane, ruppert's reagent, tms-cf3, tfmtms, silane, trimethyl trifluoromethyl, unii-a009786qpj, trimethylsilyl trifluoromethane, ruppert-prakash reagent | |
| trimethyl(trifluoromethyl)silane |
Specifications
| 54°C to 55°C | |
| C5H11F3Si | |
| MFCD00145454 | |
| 4241868 | |
| trifluoromethyl trimethylsilane, trimethyl trifluoromethyl silane, trifluoromethyltrimethylsilane, ruppert's reagent, tms-cf3, tfmtms, silane, trimethyl trifluoromethyl, unii-a009786qpj, trimethylsilyl trifluoromethane, ruppert-prakash reagent | |
| MTYSDPUZDZURPP-UHFFFAOYSA-N | |
| trimethyl(trifluoromethyl)silane | |
| 552549 | |
| 98% | |
| Moisture sensitive | |
| (Trifluoromethyl)trimethylsilane |
| 81290-20-2 | |
| (CH3)3SiCF3 | |
| UN1993 | |
| −10°C (14°F) | |
| Soluble in alcohol,THF,ether,dichloromethane,aromatic and aliphatic hydrocarbons. Soluble in water(with white smokes). | |
| CC(C)(C)[SiH2]C(F)(F)F | |
| 156.22 | |
| 142.2 | |
| 1.3305 | |
| 0.962 |
Safety and Handling
GHS H Statement
H225-H315-H319-H335
Highly flammable liquid and vapour.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
P210-P233-P235-P240-P241-P242-P243-P261-P264b-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P312-P332+P313-P363-P370+P378q-P501c
H225-H315-H319-H335
missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
missing translation for 'einecsNumber' : 000-000-0
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only
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