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Zinc tert-butoxide, Thermo Scientific Chemicals

77.80 € - 246.00 €

Chemical Identifiers

CAS 4278-43-7
Molecular Formula C8H18O2Zn
Molecular Weight (g/mol) 211.61
MDL Number MFCD00145545
InChI Key DVGVEVPHJQJMPP-UHFFFAOYSA-N
Synonym zinc tert-butoxide, di-tert-butoxyzinc, acmc-20aj87, zinc bis 2-methylpropan-2-olate, zinc 2+ bis 2-methylpropan-2-olate, zinc 2+ ion bis 2-methylpropan-2-olate
PubChem CID 14178434
IUPAC Name zinc;2-methylpropan-2-olate
SMILES CC(C)(C)[O-].CC(C)(C)[O-].[Zn+2]
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Products 2
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Product Code Brand Quantity Price Quantity & Availability  
11328648
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Thermo Scientific Alfa Aesar
040718.MD
250 mg
77.80 €
250mg
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11338648
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Thermo Scientific Alfa Aesar
040718.03
1 g
246.00 €
1g
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Description

Description

A sol-gel process has been developed for the chemical synthesis of ZnS at room temperature using zinc tert-butoxide and H 2 S as precursors in a toluene solution. The key step that enables this zinc-mediated epoxidation to be catalytic may be the equilibrium between zinc peroxide (R)-15 and zinc tert-butoxide (R)-16 in the presence of t-BuOOH. An additional important feature that renders the dual catalytic cycles feasible is the poor reactivity of zinc tert-butoxide toward the iridium-bound cationic intermediate, whereby the requisite deprotonation process is effectively mediated by zinc tert-butoxide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

4278-43-7
211.61
DVGVEVPHJQJMPP-UHFFFAOYSA-N
14178434
CC(C)(C)[O-].CC(C)(C)[O-].[Zn+2]
C8H18O2Zn
MFCD00145545
zinc tert-butoxide, di-tert-butoxyzinc, acmc-20aj87, zinc bis 2-methylpropan-2-olate, zinc 2+ bis 2-methylpropan-2-olate, zinc 2+ ion bis 2-methylpropan-2-olate
zinc;2-methylpropan-2-olate

Specifications

4278-43-7
Odorless
Zn[OC(CH3)3]2
UN3181
zinc tert-butoxide, di-tert-butoxyzinc, acmc-20aj87, zinc bis 2-methylpropan-2-olate, zinc 2+ bis 2-methylpropan-2-olate, zinc 2+ ion bis 2-methylpropan-2-olate
DVGVEVPHJQJMPP-UHFFFAOYSA-N
zinc;2-methylpropan-2-olate
14178434
Powder
White to Yellow
C8H18O2Zn
MFCD00145545
Moisture sensitive
Insoluble in water.
CC(C)(C)[O-].CC(C)(C)[O-].[Zn+2]
211.61
211.61
Zinc tert-butoxide
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Safety and Handling

Safety and Handling

GHS H Statement
H228-H315-H319-H335
Flammable solid.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P210-P240-P241-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P370+P378q-P501c

H228-H315-H319-H335

missing translation for 'dotInformation' : Transport Hazard Class: 4.1; Packing Group: III; Proper Shipping Name: METAL SALTS OF ORGANIC COMPOUNDS, FLAMMABLE, N.O.S.

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Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only

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