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2-(2-Bromoethyl)-1,3-dioxane, 98%, Thermo Scientific Chemicals Product Code.: 11394384
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2-(2-Bromoethyl)-1,3-dioxane, 98%, Thermo Scientific Chemicals

Product Code. 11394384
10 g
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Quantity:
10 g
50 g
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Product Code. 11394384

Brand: Thermo Scientific Alfa Aesar L00958.09

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Description

2-(2-Bromoethyl)-1,3-dioxane, Provides a useful means of introducing a masked β-formylethyl group. In comparison with the corresponding dioxolane (following entry), the dioxane is more stable to acid, and the Grignard is thermally stable. Reaction of the Grignard with an acid chloride gives the ketone in high yield without further reaction to the tertiary alcohol. Subsequent hydrolysis of the 1,3-dioxane gives the -ketoaldehyde. It is also used as a pharmaceutical intermediate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
2-(2-Bromoethyl)-1,3-dioxane, Provides a useful means of introducing a masked ß-formylethyl group. In comparison with the corresponding dioxolane (following entry), the dioxane is more stable to acid, and the Grignard is thermally stable. Reaction of the Grignard with an acid chloride gives the ketone in high yield without further reaction to the tertiary alcohol. Subsequent hydrolysis of the 1,3-dioxane gives the -ketoaldehyde. It is also used as a pharmaceutical intermediate.

Solubility
It is not soluble in water but soluble in organic solvent such as ethanol.

Notes
Air, Heat sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 33884-43-4
Molecular Formula C6H11BrO2
Molecular Weight (g/mol) 195.06
MDL Number MFCD00006567
InChI Key KXMZOKKPQZRPRN-UHFFFAOYNA-N
Synonym 2-2-bromoethyl-1,3-dioxane, 1,3-dioxane, 2-2-bromoethyl, 3-bromopropionaldehyde trimethylene acetal, 2 2-bromoethyl-1,3-dioxane, 2-2-bromoethyl-1,3 dioxane, bromoethyl-1,3-dioxane, acmc-209i3o, 2-2-bromoetyl 1,3-dioxane, wmdhqehpovoeog-uhfffaoysa, 2-2-bromoethyl 1,3-dioxaneShow MoreShow Less
PubChem CID 520656
SMILES CC(Br)C1OCCCO1

Specifications

Density 1.434
Boiling Point 67°C to 70°C (3 mmHg)
Flash Point 96°C (204°F)
Refractive Index 1.482
Quantity 10 g
Beilstein 1421628
Solubility Information It is not soluble in water but soluble in organic solvent such as ethanol.
IUPAC Name 2-(2-bromoethyl)-1,3-dioxane
Formula Weight 195.06
Percent Purity 98%
Chemical Name or Material 2-(2-Bromoethyl)-1,3-dioxane
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5 results found
Lot Number Certificate Type Date Catalog Number
Lot Number10241305 Certificate TypeCertificate of Analysis Date20/06/2022 Catalog NumberL00958.18,L00958.09
Lot Number10206861 Certificate TypeCertificate of Analysis Date07/12/2021 Catalog NumberL00958.18,L00958.09
Lot Number10225932 Certificate TypeCertificate of Analysis Date07/12/2021 Catalog NumberL00958.18,L00958.09
Lot NumberE02T005 Certificate TypeCertificate of Analysis Date07/12/2021 Catalog NumberL00958.18,L00958.09
Lot Number10140879 Certificate TypeCertificate of Analysis Date06/12/2021 Catalog NumberL00958.18,L00958.09

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