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  5. L-(+)-Valinol, 97%, Thermo Scientific Chemicals

L-(+)-Valinol, 97%, Thermo Scientific Chemicals

Product Code. 11327686
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Quantity:
1 g
5 g
25 g

Description

L-(+)-Valinol reacts with aldehydes and nitriles to form imines and oxazolines, respectively, for asymmetric synthesis. It is also used for preparation of 4-isopropyloxazolidinones, employed in stereocontrolled aldol and alkylation reactions, synthesis of chiral 2-thiazolidinethiones for aldol reactions, asymmetric alkylation of condensation product with keto acids, asymmetric reactions of its amidines and imines and oxidation of N-protected derivative to the aldehyde.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
L-(+)-Valinol reacts with aldehydes and nitriles to form imines and oxazolines, respectively, for asymmetric synthesis. It is also used for preparation of 4-isopropyloxazolidinones, employed in stereocontrolled aldol and alkylation reactions, synthesis of chiral 2-thiazolidinethiones for aldol reactions, asymmetric alkylation of condensation product with keto acids, asymmetric reactions of its amidines and imines and oxidation of N-protected derivative to the aldehyde.

Solubility
Soluble in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents. It is sensitive to air. Store under dry inert gas.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 2026-48-4
Molecular Formula C5H13NO
Molecular Weight (g/mol) 103.17
MDL Number MFCD00064296
InChI Key NWYYWIJOWOLJNR-RXMQYKEDSA-N
Synonym l-valinol, s-+-2-amino-3-methyl-1-butanol, 2s-2-amino-3-methylbutan-1-ol, l-+-valinol, h-valinol, s-2-amino-3-methylbutan-1-ol, s-2-amino-3-methyl-1-butanol, 1-butanol, 2-amino-3-methyl-, 2s, s-2-amino-3-methyl-butan-1-ol
PubChem CID 640993
IUPAC Name (2S)-2-amino-3-methylbutan-1-ol
SMILES CC(C)[C@H](N)CO

Specifications

Refractive Index 1.4548
Density 0.926
Boiling Point 80°C to 81°C (8mmHg)
Melting Point 30°C to 35°C
Quantity 25 g
Flash Point 78°C (172°F)
Optical Rotation +17° (c=10 in Ethanol)
Sensitivity Air sensitive
Beilstein 1719137
Solubility Information Soluble in water.
Formula Weight 103.17
Percent Purity 97%
Chemical Name or Material L-(+)-Valinol
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