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  8. trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min, Thermo Scientific Chemicals

trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min, Thermo Scientific Chemicals

Product Code. 11335988
1 g
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Quantity:
1 g
5 g
25 g
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Description

Hydrogenation, hydrosilation, carbonylation, oxidation, and C-C bond formation

As a catalyst of choice in hydrogenation, hydrosilation, carbonylation, oxidation, elimination, reduction, allyl aceate isomerization, dimerization of 1,3-dienes, and C-C bond formation such as Negishi coupling, Suzuki coupling, Kumada coupling, Sonogashira coupling, Heck coupling and Sonogashira-Hagihara coupling reactions. Used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furoquinolines, diphenylacetylenes, and several other compounds.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 13965-03-2
Molecular Formula C36H30Cl2P2Pd
Molecular Weight (g/mol) 701.90
MDL Number MFCD00009593
InChI Key YNHIGQDRGKUECZ-UHFFFAOYSA-L
Synonym bis triphenylphosphine palladium ii dichloride, bis triphenylphosphine palladium ii chloride, dichlorobis triphenylphosphine palladium, bis triphenylphosphine palladium chloride, bis triphenylphosphine palladiuml ii dichloride, palladium 2+ ; triphenylphosphane; dichloride, trans-dichlorobis triphenylphosphine palladium ii 1g
PubChem CID 131664180
IUPAC Name ethane;methane;palladium(2+);triphenylphosphane;dichloride
SMILES [Cl-].[Cl-].[Pd++].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point ∼310°C (decomposition)
Color Yellow
Odor Odorless
Linear Formula PdCl2[P(C6H5)3]2
Quantity 1 g
Sensitivity Hygroscopic
Solubility Information Insoluble in water. Soluble in benzene,and toluene.
Formula Weight 701.91
Concentration or Composition (by Analyte or Components) Pd 14.0% min.
Physical Form Crystalline
Chemical Name or Material trans-Dichlorobis(triphenylphosphine)palladium(II)
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Safety and Handling

Product Identifier
  • trans-Dichlorobis(triphenylphosphine)palladium(II)
 Hazard Category
  • LONG-TERM AQUATIC HAZARD Chronic 4
 Hazard Statement
  • H413-May cause long lasting harmful effects to aquatic life.
 Precautionary Statement
  • P273-Avoid release to the environment.
  • P501b-Dispose of contents/container in accordance with local/regional/national/international regulations.
 Supplemental information
  • MIXTURE LIST-Contains : Dichlorobis(triphenylphosphine)palladium
SDS

RUO – Research Use Only

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